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1. 发明专利:一种窄帶隙铁电半导体纳米颗粒、其制备方法及应用
申请专利号:202011252498.2
发明(设计)人:刘孝娟 姚明彩 徐兰兰 石强
授权公告日:授权审理中
2. 发明专利:一种窄帶隙铁电半导体纳米颗粒、其制备方法及应用
专利号:202011254367.8
发明(设计)人:刘孝娟 姚明彩
授权公告日:授权审理中
张洪杰、孟健、刘孝娟《纳米材料前沿-稀土纳米材料》第七章,化学工业出版社,2018,ISBN:9787122316707
1、稀土优化固体氧化物燃料电池阴极电催化性能
采用Pechini 方法合成了LnxBa1?xCo0.7Fe0.3O3?δ (Ln = La, Pr, Nd, x = 0.1, 0.2) 一系列不同A位稀土元素掺杂的新型单钙钛矿氧化物阴极材料。实验结果表明,适量的稀土掺杂能够有效地稳定BCF的立方结构,其中,Pr的掺杂量为x = 0.1 时具有最高的电催化活性,在700 和650 °C时,界面极化阻抗分别为0.026和0.038 Ω cm2,以H2为燃料的阳极支撑单电池峰值功率密度分别为1236.4 和905.9 mW cm?2,并且表现出优异的长期稳定性(~150 h)。